62222-28-0Relevant articles and documents
Synthetic Routes to 6,8-Dioxabicyclooctyl Pheromones from D-Glucose Derivatives. 3. Synthesis of (-)-Frontalin
Jarosz, Slawomir,Hicks, David R.,Fraser-Reid, Bert
, p. 935 - 940 (2007/10/02)
3-Deoxy-2-oxo glycosides with and without a C4 hydroxyl group are readily prepared from methyl α-D-glucopyranoside.Reaction with methylmagnesium iodide gives the C2 tertiary alcohol with an axially oriented methyl group.The epimeric tertiary alcohol can b