622403-01-4Relevant academic research and scientific papers
Chiral cyclotrisiloxanes
Tanaka, Ryoji,Kowase, Susumu,Unno, Masafumi
supporting information; experimental part, p. 9235 - 9237 (2011/01/10)
We have synthesized and separated the enantiomer pair of chiral cyclotrisiloxanes for the first time. Three-blade propeller-like alignment of three phenyl groups in tri(2-butyl)triphenylcyclotrisiloxane induced a positive Cotton effect with (R)-2-butyl group, and a negative effect with (S)-2-butyl substituent. The Royal Society of Chemistry.
