62255-44-1

Basic information

• Product Name: 1-O-acetyl-2,3,5-tris-O-(benzyl)-α, β-D-arabinofuranose
• Synonyms: 1-O-acetyl-2,3,5-tris-O-(benzyl)-α, β-D-arabinofuranose
• CAS NO: 62255-44-1
• Molecular Weight: 462.543
• Mol File: 62255-44-1.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: 1-O-acetyl-2,3,5-tris-O-(benzyl)-α, β-D-arabinofuranose(CAS DataBase Reference)
• NIST Chemistry Reference: 1-O-acetyl-2,3,5-tris-O-(benzyl)-α, β-D-arabinofuranose(62255-44-1)
• EPA Substance Registry System: 1-O-acetyl-2,3,5-tris-O-(benzyl)-α, β-D-arabinofuranose(62255-44-1)

Safety Data

• Hazardous Substances Data: 62255-44-1(Hazardous Substances Data)

Upstream product

• 160549-10-0 2,3,5-tri-O-benzyl-D-arabinofuranose 
• 108-24-7 acetic anhydride 
• 75-36-5 acetyl chloride 

Downstream Products

• 148744-13-2 Diphenyl(2,3,5-tri-O-benzyl-β-D-arabinofuranosyl)phosphine Oxide 
• 93041-21-5 1-O-acetyl-2,3-O-bis(phenylmethyl)-α-D-arabinofuranose 
• 70613-79-5 2,3,5-tri-O-benzyl-D-arabinofuranosyl bromide 
• 153481-95-9 (2R,3R,4S)-3,4-Bis-benzyloxy-2-benzyloxymethyl-5-phenylsulfanyl-tetrahydro-furan 
• 1333119-51-9 C₅₄H₅₂O₁₃ 
• 765274-06-4 4-penten-1-yl 2,3,5-tri-O-benzyl-α-D-arabinofuranoside 
• 160549-10-0 2,3,5-tri-O-benzyl-D-arabinofuranose 
• 1402833-58-2 S-acetyl-2,3,5-tris-O-(benzyl)-1-thio-β-D-arabinofuranose 
• 52492-41-8 2,3,5-Tri-O-benzyl-1-brom-D-arabinofuranose 
• 52492-40-7 2,3,5-tri-O-benzyl-α-D-arabinofuranosyl bromide 

Relevant articles and documents

Diastereoselective Synthesis of α-C-Arabinofuranosyl Glycine

Exploiting N-(tert-butoxycarboxyl)-2-(tert-butyldimethylsiloxy)pyrrole (TBSOP) as a masked glycine anion equivalent, a short enantiospecific synthesis of the title C-glycosyl α-aminoacid 5 was devised and executed, via diastereospecific α-C-glycosylation

Acid catalyzed rearrangement of vinyl and ketene acetals

Substituted vinyl and ketene acetals undergo smooth oxygen-to-carbon rearrangement with a catalytic amount of TMSOTf to afford chain-extended ketones or esters, respectively. The developed procedure has been applied to the stereoselective synthesis of C-glycosides from the corresponding anomeric vinyl ethers.

Arabinofuranosides from mycobacteria: Synthesis of a highly branched hexasaccharide and related fragments containing β-arabinofuranosyl residues

The synthesis of 11 oligosaccharides (4-14) containing β-arabinofuranosyl residues is reported. The glycans are all fragments of two polysaccharides, arabinogalactan and lipoarabinomannan, which are found in the cell wall complex of mycobacteria. In the preparation of the targets, the key step was a low-]temperature glycosylation reaction that installed the β-arabinofuranosyl residues with good to excellent stereocontrol.