62351-54-6Relevant articles and documents
Iron porphyrin-catalyzedN-trifluoroethylation of anilines with 2,2,2-trifluoroethylamine hydrochloride in aqueous solution
Guo, Cancheng,Guo, Yongjia,Liu, Qiang,Ren, Shuang,Xu, Guiming
, p. 20322 - 20325 (2021/06/26)
An iron porphyrin-catalyzedN-trifluoroethylation of anilines has been developed with 2,2,2-trifluoroethylamine hydrochloride as the fluorine source. This one-pot N-H insertion reaction is conductedviacascade diazotization/N-trifluoroethylation reactions.
PALLADIUM-CATALYZED ARYLATION OF FLUOROALKYLAMINES
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Paragraph 0067; 0079, (2016/12/01)
Methods for synthesizing trifluoroethyl, difluoroethyl, pentafluoropropyl, and difluorophenethyl anilines by palladium-catalyzed coupling of fluoroalkylamines with aryl bromides and aryl chlorides are provided herein. The reaction is conducted with a weak