62384-74-1Relevant academic research and scientific papers
Reactions of propargylic bromides with sodium sulfinates
Chang, Meng-Yang,Wu, Ming-Hao
supporting information, p. 411 - 416 (2014/03/21)
A one-pot, palladium-catalyzed synthesis of substituted 2,3-bissulfonylpropenes starting with propargylic bromides and sodium sulfinates (RSO2Na) in the presence of n-Bu4NF under refluxing aqueous 1,4-dioxane conditions for eight hours in moderate yields is described. Georg Thieme Verlag Stuttgart. New York.
Revisiting nucleophilic substitution reactions: Microwave-assisted synthesis of azides, thiocyanates, and sulfones in an aqueous medium
Ju, Yuhong,Kumar, Dalip,Varma, Rajender S.
, p. 6697 - 6700 (2007/10/03)
A practical, rapid, and efficient microwave (MW) promoted synthesis of various azides, thiocyanates, and sulfones is described in an aqueous medium. This general and expeditious MW-enhanced nucleophilic substitution approach uses easily accessible starting materials such as halides or tosylates in reaction with alkali azides, thiocyanates, or sulfinates in the absence of any phase-transfer catalyst, and a variety of reactive functional groups are tolerated.
REGIO- AND STEREOCONTROLLED SYNTHESIS OF ALLYLIC p-TOLYL SULFONES CATALYZED BY PALLADIUM (0) COMPLEX
Inomata, Katsuhiko,Yamamoto, Taku,Kotake, Hiroshi
, p. 1357 - 1360 (2007/10/02)
The reaction of allyl esters with sodium p-tolylsulfinate in tetrahydrofuran and methanol catalyzed by Pd(PPh3)4 gave the regio- and stereocontrolled allylic p-tolyl sulfones in good yields at room or lower temperature.
