62417-02-1Relevant articles and documents
Highly efficient and selective deprotection method for prenyl, geranyl, and phytyl ethers and esters using borontrifluoride-etherate
Narender,Venkateswarlu,Madhur,Reddy, K. Papi
, p. 26 - 33 (2012/10/30)
An efficient, simple, and practical method has been developed for the deprotection of prenyl, geranyl, and phytyl ethers and esters of aromatic and aliphatic compounds using borontrifluoride-etherate (BF3· OEt2) at room temperature in good to excellent yields for the first time. Supplemental materials are available for this article. Go to the publisher's online edition of Synthetic Communications to view the free supplemental file. Copyright Taylor & Francis Group, LLC.
Synthesis of the naturally occurring prenylated coumarins balsamiferone and cedrelopsin by domino reactions
Patre, Rupesh E.,Parameswaran, Perunninakulath S.,Tilvea, Santosh G.
experimental part, p. 68 - 76 (2011/06/19)
Regioselective one step synthesis of naturally occurring prenyl coumarin balsamiferone is described using domino Wittig reaction, 3,3-sigmatropic rearrangements and deprenylation, while regioselective synthesis of cedrelopsin is described via domino Witti
Cascade wittig reaction-double claisen and cope rearrangements: One-pot synthesis of diprenylated coumarins gravelliferone, balsamiferone, and 6,8-diprenylumbelliferone
Patre, Rupesh E.,Shet, Jyoti B.,Parameswaran, Perunninakulath S.,Tilve, Santosh G.
experimental part, p. 6488 - 6490 (2011/02/23)
A cascade Wittig reaction-double Claisen and Cope rearrangements has been employed for a one-pot synthesis of diprenylated coumarins gravelliferone, balsamiferone, and 6,8-diprenylumbelliferone from a common precursor 2,4-diprenyloxybenzaldehyde.