62459-19-2

Basic information

• Product Name: 2,4(1H,3H)-Pyrimidinedione, 5,5-dibromodihydro-6-hydroxy-6-methyl-
• CAS NO: 62459-19-2
• Molecular Formula: C5H6Br2N2O3
• Molecular Weight: 301.922
• Mol File: 62459-19-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2,4(1H,3H)-Pyrimidinedione, 5,5-dibromodihydro-6-hydroxy-6-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 2,4(1H,3H)-Pyrimidinedione, 5,5-dibromodihydro-6-hydroxy-6-methyl-(62459-19-2)
• EPA Substance Registry System: 2,4(1H,3H)-Pyrimidinedione, 5,5-dibromodihydro-6-hydroxy-6-methyl-(62459-19-2)

Safety Data

• Hazardous Substances Data: 62459-19-2(Hazardous Substances Data)

Upstream product

• 626-48-2 6-Methyluracil 
• 1461-67-2 5-iodine-6-methyl-1H-pyrimidine-2,4-dione 

Downstream Products

• 15018-56-1 5-bromo-6-methyluracil 
• 511-67-1 5,5-dibromobarbituric acid 

Relevant articles and documents

Chemical Properties of 6-Methyluracil-5-carbaldehyde Oxime

Oxidative chlorination of 6-methyluracil-5-carbaldehyde oxime in a two-phase system gave 7V-hydroxy-6-methyluracil-5-carboximidoyl chloride, and its bromination afforded ipso-substitution products, 5-bromo-6-methyluracil and 5,5-dibromo-6-hydroxy-6-methyl-5,6-dihydrouracil. The reaction of the title compound with acetic anhydride led to the formation of 6-methyluracil-5-carbonitrile or O-acetyl derivative, depending on the temperature. 7V-Hydroxy-6-methyluracyl-5-carboximidoyl chloride reacted with acetic acid at 100°C or with potassium iodide in boiling acetone to produce uracil-5-hydroxamic acid which was converted with high yields into the corresponding methyl ester and hydroximic acid amide. Quaternary ammonium salts were obtained by reactions of N-hydroxy-6-methyluracil-5-carboximidoyl chloride with pyridine and 1-methyl-1H-imidazole.