6252-34-2Relevant academic research and scientific papers
PROCESS AND COMPOUNDS FOR PREPARATION OF CANNABINOIDS
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Paragraph 0057; 0062-0063, (2020/06/05)
The invention involves condensation of various derivatives of cyclic alkene alcohols of Formula (II) or Formula (III) where, R1 is alkyl, aryl, alkyl aryl or heterocyclic carbamoyl. R2 is either R1 as mentioned earlier or an acyl group, -C(=O)-R3 where, R3 is selected from a group comprising (subst)C1-C12 alkyl, (subst)aryl, alkyl aryl with olivetol to get (-)-trans-?9-tetrahydrocannabinol (also known as Dronabinol, Formula (I)). The process disclosed provides high purity of dronabinol at crude stage making it easy for purification.
ELECTROPHILIC ADDITION OF LEAD TETRAACETATE TO 2-CARENE IN AN ACIDIDIC MEDIUM
Arbuzov, B. A.,Isaeva, Z. G.,Belyaeva, M. G.,Ratner, V. V.,Kataeva, O. N.,et al.
, p. 117 - 119 (2007/10/02)
Oxidation of 2-carene by lead tetraacetate in acetic acid afforded p-menth-1(10),2-dien-7-ol, 2-acetyl-6,6-dimethylbicyclohexane, p-menth-2-ene-1α,7-diol, p-menth-1-ene-3β,7-diol, and 2-(m-tolyl)propanol-2.Keywords: oxidation, lead tetraacetate, 2-carene, benzene, acetic acid, medium polarity.
Total Synthesis of (+)-Balanitol and of (+)-Selin-4-(15)-ene-1β,11-diol
Anglea, Timothy A.,Pinder, A. Reginald
, p. 5537 - 5544 (2007/10/02)
(+)-Balanitol (1) and (+)-selin-4-(15)-ene-1β,11-diol (2), two recently isolated naturally occurring eudesmanoid bicyclic sesquiterpene alcohols, have been synthesized stereoselectively by a route involving a photocycloaddition of a cyclobutene and
