87791-00-2Relevant academic research and scientific papers
PROCESS AND COMPOUNDS FOR PREPARATION OF CANNABINOIDS
-
Paragraph 0067, (2020/06/05)
The invention involves condensation of various derivatives of cyclic alkene alcohols of Formula (II) or Formula (III) where, R1 is alkyl, aryl, alkyl aryl or heterocyclic carbamoyl. R2 is either R1 as mentioned earlier or an acyl group, -C(=O)-R3 where, R3 is selected from a group comprising (subst)C1-C12 alkyl, (subst)aryl, alkyl aryl with olivetol to get (-)-trans-?9-tetrahydrocannabinol (also known as Dronabinol, Formula (I)). The process disclosed provides high purity of dronabinol at crude stage making it easy for purification.
Biotransformation of terpenic compounds by fungi. I. Metabolism of R-(+)-pulegone
Ismaili-Alaoui,Benjilali,Buisson,Azerad
, p. 2349 - 2352 (2007/10/02)
R-(+)-Pulegone 1 is converted by several fungal strains to new regioselectively hydroxylated compounds. Epoxidation of the double bond does not seem to be responsible for the main observed hydroxylation pattern.
Selectivity and Reactivity in Some Oxidations with Pentavalent and Hexavalent Chromium Reagents: A Short Synthesis of Norbisabolide
Kuchibhotla, Uma,Chakraborty, T. K.,Chandrasekaran, S.
, p. 1216 - 1218 (2007/10/02)
Selective oxidative cyclization of the t-hydroxyolefin (5) with pyridinium chlorochromate leads to a simple synthesis of norbisabolide (4).On the other hand, α-terpineol (7) on treatment with chromium(V) reagent undergoes facile oxidative cleavage followed by cyclization to give homoterpenyl methyl ketone (8).
