62547-81-3

Basic information

• Product Name: ethyl 1-(3-bromopropyl)-2-oxocyclohexanecarboxylate
• CAS NO: 62547-81-3
• Molecular Formula: C₁₂H₁₉BrO₃
• Molecular Weight: 291.1815
• Mol File: 62547-81-3.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 351.4°C at 760 mmHg
• Flash Point: 166.3°C
• Density: 1.307g/cm³
• Vapor Pressure: 4.13E-05mmHg at 25°C
• Refractive Index: 1.495
• CAS DataBase Reference: ethyl 1-(3-bromopropyl)-2-oxocyclohexanecarboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl 1-(3-bromopropyl)-2-oxocyclohexanecarboxylate(62547-81-3)
• EPA Substance Registry System: ethyl 1-(3-bromopropyl)-2-oxocyclohexanecarboxylate(62547-81-3)

Safety Data

• Hazardous Substances Data: 62547-81-3(Hazardous Substances Data)

Upstream product

• 1655-07-8 ethyl 2-oxocyclohexane carboxylate 
• 109-64-8 1,3-dibromo-propane 

Downstream Products

• 51584-60-2 3-(2-Oxocyclohexyl)propyl-triphenylphosphoniumbromid 
• 259235-24-0 1-(3-benzenesulfinyl-propyl)-2-oxo-cyclohexanecarboxylic acid ethyl ester 
• 259235-30-8 2-benzenesulfinyl-spiro[4.5]decane-1,6-dione 
• 6279-91-0 ethyl 2-oxo-1-propylcyclohexanecarboxylate 
• 110528-55-7 5-Oxo-cyclononanecarboxylic acid ethyl ester 
• 101493-22-5 Ethyl cis-6-hydroxybicyclo[4.3.0]nonane-1-carboxylate 
• 10468-37-8 2-(3'-bromopropyl)cyklohexanone 

Relevant articles and documents

A general strategy to spiro[4.n]alk-2-ene-1,6-diones and spiro[5.n]alk- 2-ene-1,7-diones via intramolecular acylation of α-sulfinyl carbanions

A convenient and general synthetic method for spiro[4.n]alk-2-ene-1,6- diones and spiro[5.n]alk-2-ene-1,7-diones, which involves the intramolecular acylation of an α-sulfinyl carbanion, is described.

NOVEL FREE RADICAL RING-EXPANSION REACTIONS

A novel free radical initiated ring expansion of haloalkyl β-keto esters is described.Following alkylation of the β-keto ester with the appropriate dihalide, the resulting halide is treated at reflux with tri-n-butyltin hydride.Rearrangement to the homolo