62547-81-3Relevant academic research and scientific papers
A general strategy to spiro[4.n]alk-2-ene-1,6-diones and spiro[5.n]alk- 2-ene-1,7-diones via intramolecular acylation of α-sulfinyl carbanions
Pohmakotr, Manat,Bunlaksananusorn, Tanasri,Tuchinda, Patoomratana
, p. 377 - 380 (2007/10/03)
A convenient and general synthetic method for spiro[4.n]alk-2-ene-1,6- diones and spiro[5.n]alk-2-ene-1,7-diones, which involves the intramolecular acylation of an α-sulfinyl carbanion, is described.
Synthesis of (±)-nitramine and (±)-isonitramine by utilizing stereoselective reduction of ethyl 1-(3-bromopropyl)-2-oxocyclohexanecarboxylate
Senboku, Hisanori,Hatazawa, Mamoru,Orito, Kazuhiko,Tokuda, Masao
, p. 413 - 420 (2007/10/03)
Formal synthesis of (±)-nitramine (1) and (±)-isonitramine (2) was achieved. Thus, the reduction of ethyl 1-(3-bromopropyl)-2-oxocyclohexanccarboxylate (6) with NaBH4 in MeOH gave the corresponding cyclohexanol (7) having cis geometry between h
NOVEL FREE RADICAL RING-EXPANSION REACTIONS
Dowd, Paul,Choi, Soo-Chang
, p. 77 - 90 (2007/10/02)
A novel free radical initiated ring expansion of haloalkyl β-keto esters is described.Following alkylation of the β-keto ester with the appropriate dihalide, the resulting halide is treated at reflux with tri-n-butyltin hydride.Rearrangement to the homolo
