62563-15-9

Usage

Uses

Used in Pharmaceutical Industry:
(-)-DIBUTYL-D-TARTRATE is used as a chiral resolving agent for the separation and purification of enantiomers. This is crucial in drug development and production, as it provides optically pure compounds that are essential for the efficacy and safety of pharmaceuticals.
Used in Asymmetric Synthesis:
(-)-DIBUTYL-D-TARTRATE is used as a chiral ligand in asymmetric synthesis, enabling the production of enantiomerically pure compounds. This is vital for the creation of biologically active molecules with specific stereochemistry, which is important for their therapeutic effects.
Used in Food and Beverage Industry:
(-)-DIBUTYL-D-TARTRATE is used as a flavoring agent in the food and beverage industry. Its chiral nature contributes to the unique taste profiles of various products, enhancing the sensory experience for consumers.
Used in Organic Synthesis:
(-)-DIBUTYL-D-TARTRATE is used in the synthesis of various organic compounds, leveraging its chiral properties to facilitate stereoselective reactions and asymmetric catalysis. This is important for the production of complex molecules with specific spatial arrangements, which are often required in advanced chemical and pharmaceutical applications.

InChI:InChI=1/C12H22O6/c1-3-5-7-17-11(15)9(13)10(14)12(16)18-8-6-4-2/h9-10,13-14H,3-8H2,1-2H3/t9-,10-/m0/s1

Upstream product

• 71-36-3 butan-1-ol 
• 87-69-4 L-Tartaric acid 
• 147-71-7 D-tartaric acid 

Downstream Products

• 6295-06-3 butyl glyoxalate 

Relevant academic research and scientific papers

Zn(OTf)2-promoted chemoselective esterification of hydroxyl group bearing carboxylic acids

Selective esterification of aliphatic and aromatic carboxylic acids with various alcohols is studied using triphenylphosphine, I2, and a catalytic amount of Zn(OTf)2. Use of this catalyst allows the formation of esters at a faster rate with good to excellent yield by activating the in situ generated acyloxyphosphonium ion intermediate. During the esterification process, both their aromatic and aliphatic hydroxyl groups are fully preserved from transesterification. The results show that the bulkiness and the reactivity of this doubly activated intermediate III control the selectivity and the rate of the reaction, respectively. The method is also useful for direct amidation reactions.

Superoxide dismutase mimetics. Part 2: Synthesis and structure-activity relationship of glyoxylate- and glyoxamide-derived metalloporphyrins

Novel glyoxylate- and glyoxamide-derived metalloporphyrins 26-58 were synthesized and evaluated as potential superoxide dismutase (SOD) mimetics. Relative to previously studied MnTBAP analogues, the glyoxylate-derived metalloporphyrins 32, 39, and 54 and glyoxamide-derived metalloporphyrin 49, exhibited enhanced activity in the SOD assay and the majority of the analogues in the current series showed enhanced inhibition of lipid peroxidation and catalase activity.

Substituted porphyrins

The present invention relates, in general, to a method of modulating physiological and pathological processes and, in particular, to a method of modulating cellular levels of oxidants and thereby processes in which such oxidants are a participant. The invention also relates to compounds and compositions suitable for use in such methods. Compounds of the invention include those of Formula I.