62567-87-7Relevant academic research and scientific papers
Oxidative nucleophilic substitution of hydrogen in nitroarenes with phenylacetic acid derivatives
Ma?kosza, Mieczys?aw,Kamieńska-Trela, Krystyna,Paszewski, MacIej,Bechcicka, Ma?gorzata
, p. 11952 - 11964 (2005)
Oxidative nucleophilic substitution of hydrogen (ONSH) in nitroarenes with carbanion of isopropyl phenyl acetate gives various products depending on the conditions and oxidant. The reaction carried out in liquid ammonia and KMnO 4 oxidant gives
Active and Recyclable Catalytic Synthesis of Indoles by Reductive Cyclization of 2-(2-Nitroaryl)acetonitriles in the Presence of Co-Rh Heterobimetallic Nanoparticles with Atmospheric Hydrogen under Mild Conditions
Choi, Isaac,Chung, Hyunho,Park, Jang Won,Chung, Young Keun
, p. 5508 - 5511 (2016/11/17)
A cobalt-rhodium heterobimetallic nanoparticle-catalyzed reductive cyclization of 2-(2-nitroaryl)acetonitriles to indoles has been achieved. The tandem reaction proceeds without any additives under the mild conditions (1 atm H2 and 25 °C). This procedure could be scaled up to the gram scale. The catalytic system is significantly stable under these reaction conditions and could be reused more than ten times without loss of catalytic activity.
