62596-09-2Relevant academic research and scientific papers
The synthesis of cyclohexenone using l-proline immobilized on a silica gel catalyst by a continuous-flow approach
Zhi, Cong,Wang, Jiaqing,Luo, Bin,Li, Xinming,Cao, Xueqin,Pan, Yue,Gu, Hongwei
, p. 15036 - 15039 (2014/04/17)
A facile and convenient method for the synthesis of cyclohexenone compounds was developed using an l-proline immobilized silica gel catalyst combined with a continuous-flow approach. Because of the mild reaction conditions, ease of catalyst recyclability, and product isolation, this reaction approach can potentially be used in a facile scale-up reaction or in industrial applications. the Partner Organisations 2014.
Organocatalyst-mediated aldolrobinson cascade reactions: A convenient synthesis of substituted cyclohex-2-enones
Wang, Li,Gong, Qing-Ping,Liu, Xiao-Jun,Li, Yong-Hong,Huang, Ping,Wang, Bi-Qin,Zhao, Ke-Qing
experimental part, p. 138 - 139 (2011/04/15)
A convenient organocatalytic process for the chemoselective synthesis of substituted cyclohex-2-enones was developed. The cascade reaction involves a remarkable Michael addition of an acyclic ketone-based enamine onto unmodified enones. The enamine-mediated aldolRobinson cascade reactions of aromatic and aliphatic aldehydes with acetone produced substituted cyclohex-2-enones in moderate to high yields under mild reaction conditions.
5-aryl-3-methyl-2-cyclohexen-1-ones from 4-aryl-1, 4-dihydropyridines (hantzsch esters)
Martinez, Roberto,Mendoza, Hector M.,Angeles, Enrique
, p. 2813 - 2820 (2007/10/03)
Reductive cyclization of 2,6-dimethyl-3,5-dicarboxyethyl-4-aryl-1,4- dihydropyridines using sodium and methanol as solvent produces the 5-aryl-3- methyl-2-cyclohexen-1-ones.
