62603-94-5

Upstream product

• 75-15-0 carbon disulfide 
• 100-61-8 N-methylaniline 
• 74-88-4 methyl iodide 
• 4949-93-3 1-methyl-1,3-diphenyl-thiourea 
• 198488-64-1 methyl N-methyl-N,N′-diphenylcarbamimidothioate 
• 59226-53-8 N,S,N'-trimethyl-N-phenyl-isothiourea 
• 74734-11-5 1H-imidazole-1-carbodithioic acid methyl ester 

Downstream Products

• 101938-41-4 3-ethyl-5-[(N-methyl-anilino)-methylsulfanyl-methylene]-2-thioxo-thiazolidin-4-one 
• 42140-71-6 4-methyl-3-(methylthio)-4H-benzo[e][1,2,4]thiadiazine 1,1-dioxide 
• 65016-84-4 [1-Chloro-1-methylsulfanyl-meth-(Z)-ylidene]-methyl-phenyl-ammonium; chloride 
• 10219-08-6 4-bromo-N-methyl-N-(trifluoromethyl)aniline 
• 78504-10-6 N-methyl-6-methylthio-N,4-diphenyl-1,3,5-triazine-2-amine 
• 34578-03-5 methyl 4-(methyl(trifluoromethyl)amino)benzoate 
• 3012-99-5 methyl-phenyl-thiocarbamic acid S-methyl ester 
• 121983-52-6 N-benzenesulfonylamide 
• 121983-53-7 4-Chloro-N-[1-(methyl-phenyl-amino)-1-methylsulfanyl-meth-(Z)-ylidene]-benzenesulfonamide 

Relevant academic research and scientific papers

1-(Methyldithiocarbonyl)imidazole: A useful thiocarbonyl transfer reagent for synthesis of substituted thioureas

1-(Methyldithiocarbonyl)imidazole 1 and its N-methyl quaternary salt 2 have been shown to be efficient methyldithiocarbonyl and thiocarbonyl transfer reagents for the synthesis of dithiocarbamates, symmetrical and unsymmetrical mono-, di- and tri-substituted thioureas in high yields under mild and simple non-hazardous reaction conditions. (C) 2000 Elsevier Science Ltd.

A Facile Synthesis of Trifluoromethylamines by Oxidative Desulfurization-Fluorination of Dithiocarbamates

Trifluoromethylamines are easily synthesized from dithiocarbamates by a reagent system consisting of tetrabutylammonium dihydrogentrifluoride and an N-halo imide under mild conditions. When this reaction was applied to dithiocarbamates ArN(R)CS2Me at higher temperatures, the trifluoromethylation was accompanied by halogen substitution at the p-position of the Ar group. The synthesis of trifluoromethyl-substituted adenosine is also described.

Cycloaddition in Synthesis of Sulfonamide Derivatives. I. A New Method for Preparation of N-(C-Amino-alkylthiomethylene)benzenesulfonamide

A novel cycloaddition reaction of benzenesulfonyl isocyanate is reported which can serve as a new, general method for the preparation of N-(C-amino-alkylthiomethylene)benzene-sulfonamide.Benzenesulfonyl isocyanates underwent a cycloaddition re