6261-31-0

Usage

Physical state

White solid

Solubility

Soluble in organic solvents

Odor

Strong

Uses

Production of dyes, reagent in organic synthesis, chemical intermediate, manufacturing of antioxidants, lubricating oils, and pharmaceuticals

Properties

Antimicrobial and antioxidant

Handling precautions

Toxic and can cause skin and respiratory irritation

Upstream product

• 100-52-7 benzaldehyde 
• 6261-32-1 2-benzylidene-1-tetralone 
• 6261-32-1 (E)-2-benzylidene-1-tetralone 

Downstream Products

• 6261-33-2 cis-2-benzyl-1,2,3,4-tetrahydronaphthalene-1-ol 
• 6261-33-2 (1S,2R)-2-benzyl-1,2,3,4-tetrahydronaphthalen-1-ol 
• 6261-33-2 (1R,2S)-2-benzyl-1,2,3,4-tetrahydronaphthalen-1-ol 
• 77786-87-9 N-methyl carbamate de benzylidene-2 tetralol 
• 6261-32-1 (E)-2-benzylidene-1-tetralone 
• 613-59-2 2-benzylnaphthalene 
• 59082-36-9 2-(Benzylidene)-3,4-dihydronaphthalen-1(2H)-on 
• 84787-49-5 1,2-dihydro-9H-benzofluorene 

Relevant academic research and scientific papers

Palladium-Catalyzed Synthesis of α-Methyl Ketones from Allylic Alcohols and Methanol

One-pot synthesis of α-methyl ketones starting from 1,3-diaryl propenols or 1-aryl propenols and methanol as a C1 source is demonstrated. This one-pot isomerization-methylation is catalyzed by commercially available Pd(OAc)2 with H2O as the only by-product. Mechanistic studies and deuterium labelling experiments indicate the involvement of isomerization of allyl alcohol followed by methylation through a hydrogen-borrowing pathway in these isomerization-methylation reactions.

Asymmetric Hydrogenation of Racemic Allylic Alcohols via an Isomerization-Dynamic Kinetic Resolution Cascade

Prochiral racemic allylic alcohols are converted to enantioenriched chiral alcohols bearing adjacent stereocenters catalyzed by a diamine diphosphine Ru complex in the presence of tBuOK. The protocol features a broad substrate scope (56 examples) and high

Synthesis of polysubstituted quinolines via transition-metal-free oxidative cycloisomerization of o -cinnamylanilines

An efficient synthesis of 2-aryl 4-substituted quinolines from stable and readily available o-cinnamylanilines, prepared from anilines and cinnamylalcohols, has been developed. The reaction occurred via a regioselective 6-endo-trig intramolecular oxidative cyclization using KOtBu as a mediator and DMSO as an oxidant at rt. The reaction showed a broad substrate scope with good to excellent yields.

Hydroxy-Directed Hydroaluminations: A Stereoselective Approach to Cycloalkanols From β-Aryl Enones.

Various aryl substituted enones are reduced using lithium aluminum hydride to afford sterioselectively trans substituted alkanols.Mechanistic studies demonstrate 1,2-addition followed by hydroxy-directed hydroalumination of the conjugated styryl unit.