626606-14-2

Upstream product

• 19088-99-4 3-chloro-2-nitrobenzoyl chloride 
• 2687-25-4 3-methyl-1,2-benzenediamine 
• 4771-47-5 3-chloro-2-nitro-benzoic acid 

Downstream Products

• 626606-00-6 1-[2-(3-chloro-2-nitrophenyl)-4-methylbenzimidazol-1-yl]-3,3-dimethylbutan-2-ol 
• 626606-21-1 1-allyl-2-(3-chloro-2-nitrophenyl)-4-methylbenzimidazole 

Relevant academic research and scientific papers

Intermolecular SNAr of the heterocycle-activated nitro and fluoro groups-application in the synthesis of polyazamacrocyclic ligands

A new class of tetracylic benzimidazole compounds and derivatives thereof. Additionally provided is a synthetic route for the generation of these and related compounds via Intramolecular Aromatic Nucleophilic Substitution (SNAr) of the Benzimid

Intramolecular Aromatic Nucleophilic Substitution of the Benzimidazole-Activated Nitro Group

(Equation Presented) A wide range of 2-(2-nitrophenyl)-1H-benzimidazoles undergo high-yielding intramolecular SNAr of nitrite with N-pendant alkoxides under mild conditions (DMF, rt). When this operationally simple process is carried out at ele