62692-40-4

Basic information

• Product Name: Benzene, (3-bromo-3-butenyl)-
• Synonyms: Benzene,(3-bromo-3-butenyl);2-bromo-4-phenylbut-1-ene;(2-bromobut-3-enyl)benzene;4-phenyl-2-bromobut-1-ene;2-bromo-4-phenylbutene;Benzene, (3-bromo-3-butenyl)-;2-bromo-4-phenyl-1-butene;2-Brom-4-phenyl-but-1-en
• CAS NO: 62692-40-4
• Molecular Formula: C10H11Br
• Molecular Weight: 211.101
• Mol File: 62692-40-4.mol
• Article Data: 11

Chemical Properties

• Boiling Point: 243.12°C (rough estimate)
• Density: 1.2907
• Refractive Index: 1.5450
• CAS DataBase Reference: Benzene, (3-bromo-3-butenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, (3-bromo-3-butenyl)-(62692-40-4)
• EPA Substance Registry System: Benzene, (3-bromo-3-butenyl)-(62692-40-4)

Safety Data

• Hazardous Substances Data: 62692-40-4(Hazardous Substances Data)

Upstream product

• 513-31-5 2-bromoallyl bromide 
• 6921-34-2 benzylmagnesium chloride 
• 62692-29-9 C₁₆H₁₅BrO₂S 
• 100-39-0 benzyl bromide 
• 2550-26-7 4-Phenyl-2-butanone 
• 64884-77-1 4-methyl-N'-(4-phenylbutan-2-ylidene)benzenesulfonohydrazide 
• 100-44-7 benzyl chloride 
• 16520-62-0 4-Phenyl-1-butyne 
• 65674-14-8 1,2-dibromo-4-phenylbutane 
• 3112-88-7 Benzyl phenyl sulfone 

Downstream Products

• 115045-60-8 1-(3-butyl-3-butenyl)benzene 
• 115045-62-0 Trimethyl-((Z)-3-methylene-5-phenyl-pent-1-enyl)-silane 
• 1391742-82-7 2-(4-phenylbut-1-en-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 1391742-83-8 (R)-2-(4-phenylbutan-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 1415610-31-9 (R)-3-((4,4,6-trimethyl-1,3,2-dioxaborato)methyl)-5-phenylpentanoic acid phenyl amide 
• 904689-49-2 1,1,2-tribromo-2-(2-phenylethyl)cyclopropane 

Relevant articles and documents

Synthesis of functionalized cyclopropylboronic esters based on a 1,2-metallate rearrangement of cyclopropenylboronate

A procedure converting tribromocyclopropane to densely functionalized β-selenocyclopropylboronic ester using the 1,2-metallate rearrangement of a boron ate-complex has been developed. Treatment of an in situ-generated cyclopropenylboronic ester ate-complex with phenylselenenyl chloride triggered stereospecific rearrangement to produce functionalized cyclopropanes. DFT calculations for 1,2-metallate rearrangement suggested that the reaction proceeds through a seleniranium intermediate. This journal is

Synthesis of Spirocyclic Ethers by Enantioselective Copper-Catalyzed Carboetherification of Alkenols

Spirocyclic ethers can be found in bioactive compounds. This copper-catalyzed enantioselective alkene carboetherification provides 5,5-, 5,6- and 6,6-spirocyclic products containing fully substituted chiral carbon centers with up to 99 % enantiomeric exce

Regioselective Synthesis of Vinyl Halides, Vinyl Sulfones, and Alkynes: A Tandem Intermolecular Nucleophilic and Electrophilic Vinylation of Tosylhydrazones

A diazo species is trapped in an intermolecular fashion by two independent ion species in tandem at the carbene center to install an electrophile and a nucleophile on the same carbon. This metal-free concept, which is unprecedented, has been illustrated by regioselective synthesis of a variety of vinyl halides, vinyl sulfones, and alkyne derivatives. (Chemical Equation Presented).