62738-29-8Relevant academic research and scientific papers
New indigo chromophores containing disulfide donor groups
Gerke, Ralf,Fitjer, Lutz,Mueller, Peter,Uson, Isabel,Kowski, Klaus,Rademacher, Paul
, p. 14429 - 14434 (1999)
Oxidative dimerization of a mixture of the thiolanone 5 and the dithiolanone 4 yields 2c as chromophore of thioindigo 1c, and 6 and 7 as chromophores of still unknown indigo dyes. As compared to 2c, the first ionization potential of the new indigo chromophore 7 is higher, but the calculated HOMO-LUMO splitting is lower. Accordingly, its longest wavelength absorption maximum surpasses that of 2c distinctly.
