62743-71-9Relevant academic research and scientific papers
A Selective Degradation of the Exomethylene Group of Vitamin D. - A Simple Entry to 10-Oxo-19-norcholecalciferol and 10-Oxo-19-norergocalciferol
Reischl, Wolfgang
, p. 587 - 594 (2007/10/02)
Nitrile oxides, generated in situ from nitroalkanes, add exclusively to the exomethylene group of (Z)- and (E)-vitamin D3 acetates (1a, 12a) and D2 acetates (1b, 12b).The so generated spirocyclic isoxazoline derivatives are transform
Biomimetic oxidation of vitamin D by iron-sulfur model cluster and dioxygen system
Yamamoto,Imae,Yamada
, p. 4903 - 4906 (2007/10/02)
Oxidation of vitamin D3 with a combination of iron-sulfur protein model cluster, (n-Bu4N)2[Fe4S4(SPh)4], and molecular oxygen produced (5E)-10-oxo-10-norvitamin D3 and 8α-hydroxy-9,10-seco-4,6,10(19)-cholestatrien-3-one, a new type of vitamin D metabolites, mimicking biological oxidation.
