2871-23-0Relevant articles and documents
Studies on [2?+?3] cycloaddition reaction of nitrile oxides to linear dipolarophiles bearing multiple double bonds
Gucma, Miros?aw,Go??biewski, W. Marek,Michalczyk, Alicja Katarzyna
, p. 1809 - 1818 (2016)
Abstract: Site selectivity, regioselectivity, and stereoselectivity of [2?+?3] cycloaddition of benzonitrile oxides to polyunsaturated esters were examined. Site selectivity was correlated with electron charges of unsaturated carbon atoms. Structure of the products has been established by an extensive application of 1H and 13C NMR spectroscopy and electrospray ionization mass spectrometry. Graphical abstract: [Figure not available: see fulltext.]
Oxidation of natural targets by dioxiranes. 3.1 stereoselective synthesis of (all-R)-vitamin D3 triepoxide and of its 25-hydroxy derivative
Curci, Ruggero,Detomaso, Antonia,Prencipe, Teresa,Carpenter, Gene B.
, p. 8112 - 8115 (2007/10/02)
In applying dimethyldioxirane (1a) and methyl(trifluoromethyl)dioxirane (1b) to the oxyfunctionalization of vitamin D3 and of its 3-acyl derivatives, remarkable selectivities could be attained. Thus, reaction of 3β-acetylvitamin D3 (