6275-92-9Relevant academic research and scientific papers
A piperidinium-carbodithioate salt: Synthesis, crystal structure, spectral, cation-interaction and electrochemical studies
Nath, Paras,Bharty,Prasad,Butcher,Jasinski
, p. 51 - 56 (2019)
An ionic compound 4-methyl-piperidinium 4-methyl-piperidinecarbodithioate (MPMP) C6H14N+·C7H12NS2 ˉ has been synthesized from the one pot reaction of 4-methylpiperidine and carbon disulfide. The compound is well characterized on the basis of elemental analysis, IR, NMR, UV–visible and single crystal X-ray diffraction data. The compound introduces the concept of hydrogen bonding interactions in two ionic species and its effect on crystal packing. The asymmetric unit of the compound consists of 4-methyl-piperidinium cation and 4-methyl-piperidinecarbodithioate anion. Inter and intramolecular N[sbnd]H?S contacts link piperidinium cation and carbodithioate anion and stabilize the crystal packing in solid state. The compound crystallizes in monoclinic system with space group P 21/c. The interaction of the compound with different metal ion solutions is studied and it shows interesting red shifts with Co2+, Cu+, Cu2+ and Ni2+ ions which suggests that MPMP may be a useful probe for sensing of these ions. Cyclic voltammetric analysis of the compound exhibits quasi-reversible redox behaviour.
