62758-67-2Relevant academic research and scientific papers
Atropisomeric Hydrogen Bonding Control for CO2 Binding and Enhancement of Electrocatalytic Reduction at Iron Porphyrins
Aukauloo, Ally,Gotico, Philipp,Guillot, Regis,Halime, Zakaria,Leibl, Winfried,Roupnel, Lo?c,Sircoglou, Marie
, p. 22451 - 22455 (2020)
The manipulation of the second coordination sphere for improving the electrocatalytic CO2 reduction has led to breakthroughs with hydrogen bonding, local proton source, or electrostatic effects. We have developed two atropisomers of an iron por
Through-Space Electrostatic Interactions Surpass Classical Through-Bond Electronic Effects in Enhancing CO2 Reduction Performance of Iron Porphyrins
Khadhraoui, Asma,Gotico, Philipp,Leibl, Winfried,Halime, Zakaria,Aukauloo, Ally
, p. 1308 - 1315 (2021/02/05)
In his pioneering work to unravel the catalytic power of enzymes, Warshel has pertinently validated that electrostatic interactions play a major role in the activation of substrates. Implementing such chemical artifice in molecular catalysts may help impr
