62759-83-5

Usage

Uses

Methyl 4,4-dimethoxy-3-oxovalerate may be used in chemical synthesis.

General Description

Methyl 4,4-dimethoxy-3-oxovalerate is an ester. Preparation of methyl 4,4-dimethoxy-3-oxovalerate in tetrahydrofuran is reported.

InChI:InChI=1/C8H14O5/c1-8(12-3,13-4)6(9)5-7(10)11-2/h5H2,1-4H3

Upstream product

• 21983-72-2 3,3-dimethoxy-butan-2-one 
• 616-38-6 carbonic acid dimethyl ester 

Downstream Products

• 95496-35-8 2-(2,2-Dimethoxy-propionyl)-4-methyl-5-oxo-hexanoic acid methyl ester 
• 95517-30-9 (1R,2S,5S)-2-(1,1-Dimethoxy-ethyl)-2-hydroxy-5-methyl-4-oxo-cyclohexanecarboxylic acid methyl ester 
• 83220-30-8 2-(2,2-Dimethoxy-propionyl)-5-oxo-hexanoic acid methyl ester 
• 83220-32-0 2-(1,1-Dimethoxy-ethyl)-2-hydroxy-4-oxo-cyclohexanecarboxylic acid methyl ester 
• 83220-32-0 (1R,2S)-2-(1,1-Dimethoxy-ethyl)-2-hydroxy-4-oxo-cyclohexanecarboxylic acid methyl ester 
• 62993-09-3 dimethyl 4-(2-chlorophenyl)-2-(1,1-dimethoxyethyl)-6-methyl-1,4-dihydropyridine-3,5-dicarboxylate 
• 95496-38-1 (1R,2S,5S)-2-Acetyl-2-hydroxy-5-methyl-4-oxo-cyclohexanecarboxylic acid methyl ester 
• 95496-37-0 (1R,2S,4R)-2-(1,1-Dimethoxy-ethyl)-2,4-dihydroxy-cyclohexanecarboxylic acid methyl ester 
• 95496-40-5 (1R,2S,4S,5S)-2-Acetyl-2,4-dihydroxy-5-methyl-cyclohexanecarboxylic acid methyl ester 
• 95496-39-2 (1R,2S,4R)-2-Acetyl-2,4-dihydroxy-cyclohexanecarboxylic acid methyl ester 
• 71847-64-8 3-Methyl-2-oxo-4-phenylsulfanyl-cyclopent-3-enecarboxylic acid methyl ester 
• 83220-33-1 methyl 2-acetyl-4-oxo-2-cyclohexene-1-carboxylate 
• 344317-73-3 4,4-Dimethoxy-3-oxo-2-(3-oxo-cyclohexyl)-pentanoic acid methyl ester 

Relevant academic research and scientific papers

A Simple Synthesis of Anthracyclinones from 2-Acetylquinizarin

Reaction of 2-acetyl-1,4-dihydroxyanthraquinone with a variety of β-keto esters in presence of tertiary amine in MeOH afforded anthracyclinone derivatives in a one-pot addition-oxidation-aldol sequence.

Stereospecific Total Synthesis of dl-Coriolin and dl-Coriolin B

The total synthesis of the title compounds are described.The starting materials were the enedione 6 and the siloxy diene 27.Cycloaddition of these compounds afforded 28, which was converted to 30.Degradation of enone 30 gave methyl ketone 32, which upon c