71847-64-8Relevant academic research and scientific papers
SYNTHESIS OF CYCLOPENTANOID NATURAL PRODUCTS VIA VINYL PHOSPHONIUM SALTS
Cameron, Andrew G.,Hewson, Alan T.,Osammor, Matthew I.
, p. 2267 - 2270 (2007/10/02)
Cyclopentenones obtained from cyclisations involving phosphonium salts are converted to dihydrojasmone, dihydrojasmolone and known precursors of methylenomycins A and B.
A Total Synthesis of (+/-)-Methylenomycin A
Takahashi, Yasuhiro,Isobe, Kohei,Hagiwara, Hisahiro,Kosugi, Hiroshi,Uda, Hisashi
, p. 714 - 715 (2007/10/02)
A new synthesis of (+/-)-methylenomycin A (1) has been accomplished by applying the cyclisation reaction between the vinyl-lithium reagent (2) and methyl acrylate as the key step.
