62770-62-1Relevant articles and documents
SOLVENT-FREE CROSS-COUPLING REACTION, AND PRODUCTION METHOD USING SAID REACTION
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Paragraph 0311-0314; 0318, (2021/12/30)
Disclosed is a cross-coupling reaction method which forms a chemical bond selected from C—N, C—B, C—C, C—O and C—S bonds, the method comprising: preparing an aromatic compound (1) having a leaving group;preparing a compound (2) capable of undergoing a cross-coupling reaction selected from an aromatic amino compound (2-1), a diboronic acid ester or the like (2-2), an aromatic boronic acid or the like (2-3), an aromatic compound (2-4) having a hydroxyl group and an aromatic compound (2-5) having a thiol group; andperforming a cross-coupling reaction of the compound (1) with the compound (2) in the presence of a palladium catalyst, a base and a compound (4) having a carbon-carbon double bond or a carbon-carbon triple bond, in the absence of a solvent.
Phenothiazine class derivative and preparation method and application thereof
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Paragraph 0048; 0049; 0050; 0051, (2017/06/02)
The invention provides a phenothiazine class derivative and a preparation method and application thereof and relates to the technical field of organic optoelectronic materials. The optimization of molecular structure design, the phenothiazine class derivative has a better rigid structure and big-pi bond conjugate system and quite good hole-transmission capability and can be used for preparing an organic light-emitting device, and the phenothiazine class derivative high in efficiency and long in service life and serving as hole-transmission material in the organic light-emitting device is prior to an existing OLED (organic light-emitting diode) in common use. The invention further provides the preparation method of the phenothiazine class derivative, and the preparation method is simple, and raw materials are easy to obtain.
Pd-indenyl-diphosphine: An effective catalyst for the preparation of triarylamines
Yan, Meng-Qi,Yuan, Jia,Pi, Yun-Xiao,Liang, Jin-Hua,Liu, Yan,Wu, Qing-Guo,Luo, Xue,Liu, Sheng-Hua,Chen, Jian,Zhu, Xiao-Lei,Yu, Guang-Ao
supporting information, p. 451 - 454 (2016/01/12)
A new Buchwald-type diphosphine ligand has been developed for applications in Pd-catalyzed amination reactions towards the preparation of triarylamines. The catalyst can be used to perform the amination of a diverse array of aryl and heteroaryl chlorides.