62785-38-0Relevant academic research and scientific papers
Oxidative fragmentation of 1-aryl-1-cycloalkenes using cerium(IV) ammonium nitrate (CAN): Some novel observations
Nair, Vijay,Panicker, Sreeletha B,Thomas, Siji,Santhi,Mathai, Sindhu
, p. 3229 - 3234 (2007/10/03)
1-Phenyl-1-cycloalkenes undergo oxidative fragmentation in presence of CAN in methanol, affording 1,n-dicarbonyl compounds as the major products along with 1,2-dimethoxycycloalkanes. The reaction under deoxygenated conditions afforded the latter in good yields. In the presence of azide ion, fragmentation leading to the corresponding cyanoketones was observed whereas with sulfinate only the 1-methoxy-2-sulfonyl cycloalkanes were formed.
Cerium (IV) sulfate mediated oxidative addition of 1-phenylcycloalkenes and styrene derivatives in methanol: Synthesis of 1,2-dimethoxy compounds
He, Liangyou,Horiuchi, C. Akira
, p. 172 - 173 (2007/10/03)
The reaction of 1-phenylcycloalkenes and derivatives of styrene with cerium(IV) sulfate tetrahydrate in methanol leads to the formation of 1,2- dimethoxy compounds (54-89%).
CAN mediated fragmentation of 1-phenylcycloalkenes: Synthesis of monoacetals of 1,n-dicarbonyl compounds
Nair, Vijay,Panicker, Sreeletha B.
, p. 563 - 564 (2007/10/03)
Phenylcycloalkenes undergo facile oxidative fragmentation in presence of CAN in methanol giving ketoacetals of 1,n-dicarbonyl compounds.
