62785-50-6Relevant academic research and scientific papers
Reaction of triphenylphosphine oxide with ortho-dihydroxyaromatic compounds
Bidman
, p. 1545 - 1546 (2001)
Triphenylphosphine oxide was first reacted with 2,3-dihydroxynaphthalene, as well as with halo-and alkyl-substituted 1,2-dihydroxybenzenes to obtain the corresponding (ortho-naphthylenedioxy)-or (ortho-phenylenedioxy)triphenylphosphoranes.
Selective functional transformation of 1,2-diols via organophosphorus reagents
Pirat, Jean-Luc,Carteron, Michel,Maggio, Annie-Francoise,Bot, Stephanie,Cristau, Henri-Jean
, p. 609 - 612 (2007/10/03)
A new synthesis of 1,3,2λ5-dioxaphospholanes was realized by direct reaction of dibromotriphenylphosphorane with 1,2-diols. Ring opening studies were performed with or without electrophilic activation (Lewis acids or hydrogen bonding) in order to substitute selectively one of the hydroxy function.
