62787-21-7Relevant articles and documents
Copper(II) trans-bis-(glycinato): An efficient heterogeneous catalyst for cross coupling of phenols with aryl halides
Verma, Sanny,Kumar, Neeraj,Jain, Suman L.
experimental part, p. 4665 - 4668 (2012/09/05)
Copper(II) trans-bis-(glycinato) complex, easily prepared by the solid state reaction of copper(II) acetate and glycine (trans-[Cu(glyo) 2·H2O]) was found to be an efficient, recyclable, and high yielding catalyst for the Ullmann type synthesis of diaryl ethers via the cross coupling of phenols with aryl halides without using any additives at relatively low reaction temperature. The catalyst could easily be recovered by simple filtration and was reused for several runs with consistent catalytic activity.
Copper promoted C-N and C-O bond cross-coupling with phenyl and pyridylboronates
Chan, Dominic M. T.,Monaco, Kevin L.,Li, Renhua,Bonne, Damien,Clark, Charles G.,Lam, Patrick Y. S.
, p. 3863 - 3865 (2007/10/03)
Acyclic and cyclic esters, as well as anhydride (boroxine) of phenylboronic acids are efficient phenylating agents in copper promoted C-N and C-O bond cross-coupling reactions. The first successful C-N cross-coupling of a heterocyclic boronate with heteroarenes, such as indazole, has been demonstrated.
The Chemistry of Pentavalent Organobismuth Reagents. Part 7. The Possible Role of Radical Mechanisms in the Phenylation Process for Bismuth(V), and Related Lead(IV), Iodine(III), and Antimony(V) Reagents
Barton, Derek H. R.,Finet, Jean-Pierre,Giannotti, Charles,Halley, Frank
, p. 241 - 250 (2007/10/02)
The phenylation reactions of bismuth(V), lead(IV), and iodine(III) have been examined to test the presence or absence of phenyl radicals.In the case of several bismuth(V) reactions the presence of phenyl radicals has been detected, but it has been shown, by use of a large excess of radical trapping agent, that these radicals have nothing to do with the phenylation process.In the same way, the other phenylation reactions fail to respond to a large excess of a radical trap.