62790-79-8

Basic information

• Product Name: Silane, (1,1-dimethylethyl)dimethyl(2-methylphenoxy)-
• Synonyms: 2-(tert-butyldimethylsilyloxy)toluene;Silane,(1,1-dimethylethyl)dimethyl(2-methylphenoxy);tert-butyl-dimethyl-o-tolyloxy-silane;2-tert-butyldimethylsiloxytoluene;(1,1-dimethylethyl)dimethyl(2-methylphenoxy)silane;O-tert-butyldimethylsilyl 2-methylphenol
• CAS NO: 62790-79-8
• Molecular Formula: C13H22OSi
• Molecular Weight: 222.403
• Mol File: 62790-79-8.mol
• Article Data: 18

Chemical Properties

• CAS DataBase Reference: Silane, (1,1-dimethylethyl)dimethyl(2-methylphenoxy)-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, (1,1-dimethylethyl)dimethyl(2-methylphenoxy)-(62790-79-8)
• EPA Substance Registry System: Silane, (1,1-dimethylethyl)dimethyl(2-methylphenoxy)-(62790-79-8)

Safety Data

• Hazardous Substances Data: 62790-79-8(Hazardous Substances Data)

Upstream product

• 95-46-5 2-methylphenyl bromide 
• 533-18-6 2-methylphenyl acetate 
• 69739-34-0 t-butyldimethylsiyl triflate 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 95-48-7 ortho-cresol 

Downstream Products

• 95-48-7 ortho-cresol 
• 119968-49-9 tert-butyldimethyl((2-methylcyclohexyl)oxy)silane 
• 119968-49-9 tert-butyldimethyl((2-methylcyclohexyl)oxy)silane 
• 195062-59-0 2-methylphenylboronic acid pinacol ester 
• 1446840-39-6 (R)-4-(p-tolyl)-4,5-dihydrobenzo[b]oxepin-2(3H)-one 
• 1446840-35-2 (R)-4-phenyl-4,5-dihydrobenzo[b]oxepin-2(3H)-one 
• 1446841-48-0 4-phenyl-4,5-dihydrobenzo[b]oxepin-2(3H)-one 
• 1446841-17-3 C₁₇H₁₈O₃ 
• 1446841-25-3 C₂₁H₂₈N₂O₂ 

Relevant articles and documents

Synthetic Studies of the Rubellin Natural Products: Development of a Stereoselective Strategy and Total Synthesis of (+)-Rubellin C

This manuscript describes our studies of the class of natural products known as the rubellins, culminating in the total synthesis of (+)-rubellin C. These anthraquinone-based natural products contain a variety of stereochemical and architectural motifs, including a 6-5-6-fused ring system, 5 stereogenic centers, and a central quaternary center. Herein, we report our development of a strategy to target the stereochemically dense core and anthraquinone nucleus, including approaches such as a bifunctional allylboron and vinyl triflate reagent, an anthraquinone benzylic metalation strategy, and a late-stage anthraquinone introduction strategy. Our studies culminate in a successful route to highly functionalized anthraquinone-based natural product scaffolds and a stereoselective total synthesis of (+)-rubellin C. These strategies and outcomes will aid in synthetic planning toward anthraquinone-based natural products of high interest.

Asymmetric synthesis of novel spirocycles via a chiral phosphoric acid catalyzed desymmetrization

A straightforward method for the asymmetric preparation of novel lactone and lactam spirocycles is described. An initial desymmetrization via a chiral Br?nsted acid yields enantioenriched lactones which readily undergo a second cyclization to give the des

7-MEMBERED FUSED HETEROCYCLES AND METHODS OF THEIR SYNTHESIS

Disclosed are a new method for synthesizing 7-membered fused heterocycles and compounds synthesized by the new method. The method involves a dual activation strategy using an N-heterocyclic carbene catalyst as a first Lewis base and another second Lewis b