62798-94-1Relevant articles and documents
Decarboxylative trichloromethylation of aromatic aldehydes and its applications in continuous flow
Jensen, Andreas B.,Lindhardt, Anders T.
, p. 1174 - 1183 (2014/03/21)
Two new protocols for the efficient synthesis of 2,2,2- trichloromethylcarbinols, starting from aromatic aldehydes, have been developed. A combination of sodium trichloroacetate in the presence of malonic acid proved efficient for the transformation of el
Chain Reactions Induced by Cathodic Reduction
Shono, Tatsuya,Kise, Naoki,Masuda, Mitsuharu,Suzumoto, Takeshi
, p. 2527 - 2533 (2007/10/02)
Cathodic reduction of a system comprising carbon tetrachloride, chloroform, and an aldehyde led to an effective anionic chain reaction.The best current efficiency observed was about 1*104 percent .Such a chain reaction is an effective synthetic method for 1,1,1-trichloro-2-alkanols.The reaction system consisting of methyl trichloroacetate, methyl dichloroacetate, and an aldehyde and several other systems also exhibited a similar pattern of chain reaction.