628692-47-7Relevant academic research and scientific papers
P-C versus C-H bond cleavage in coordinated bis(dimethylphosphino)methane: Controlled access to either phosphinite or functionalized diphosphine complexes
Quesada, Roberto,Ruiz, Javier,Riera, Victor,Garcia-Granda, Santiago,Diaz, M. Rosario
, p. 1942 - 1943 (2007/10/03)
Treatment of fac-[Mn(CNPh)(CO)3(dmpm)]ClO4 (1) with KOH affords neutral phosphinite complex fac[Mn(PMe2O)(CNPh)(CO)3(PMe3)] (2) as a result of P-C bond cleavage on the dmpm ligand, whereas when carrying out the reaction in the presence of iodine the diphosphinoketenimine derivative fac-[MnI(CO)3-{(PMe2)2C=C=NPh}] (4) is obtained after deprotonation and further functionalization of the central carbon atom of the diphosphine.
