62870-22-8

Upstream product

• 75-03-6 ethyl iodide 
• 91596-26-8 4-((E)-1-Methyl-2-phenylsulfanyl-vinyl)-morpholine 
• 108-98-5 thiophenol 
• 3561-67-9 bis(phenylthio)methane 
• 15486-58-5 1,1-bis(phenylthio)propane 
• 5042-53-5 1-(phenylsulfanyl)acetone 

Downstream Products

• 108378-28-5 5-chloro-3-ethyl-3-phenylthiohex-5-en-2-one 
• 83182-14-3 3-phenylsulphinylpentan-2-one 
• 80538-97-2 (Z) 3-phenylthiopent-3-en-2-one 
• 109328-61-2 (E) 3-phenylthiopent-3-en-2-one 
• 79749-92-1 4-ethyl-5-methyl-4-(phenylthio)-4,5-dihydrofuran-2(3H)-one 
• 79749-92-1 4-ethyl-5-methyl-4-(phenylthio)-4,5-dihydrofuran-2(3H)-one 
• 66165-10-4 1-Methyl-2-phenylthiobutyl-phenylsulfid 

Relevant academic research and scientific papers

Synthesis of α-Phenylthio Enones and Esters of α-Phenylthio Alkenoic Acids

The title compounds can be made by a Pummerer dehydration from the corresponding saturated sulphoxides.The alkylation of anions from saturated and unsaturated ketones is described.

Scope and limitations of allyl sulphide synthesis by [1,2] and [1,3] phenylthio migration

β-Phenylthio-alcohols rearrange in acidic solution (toluene-p-sulphonic acid in benzene under reflux) to give allyl sulphides by phenylthio migration. High yields of single products useful in organic synthesis are obtained with a tertiary or secondary mig