62907-83-9Relevant academic research and scientific papers
Promoting Ethylene (co)Polymerization in Aliphatic Hydrocarbon Solvents Using tert-Butyl Substituted Nickel Catalysts
Chen, Ao,Chen, Changle,Liao, Daohong
, p. 215 - 222 (2021/12/16)
In the past few decades, the development of high-performance catalysts has been a key driving force and a center of research efforts in the field of olefin polymerization. However, a major discrepancy exists between industrial researches which utilize ali
Synthesis and structure of tetraarylcumulenes: Characterization of bond-length alternation versus molecule length
Januszewski, Johanna A.,Wendinger, Dominik,Methfessel, Christian D.,Hampel, Frank,Tykwinski, Rik R.
supporting information, p. 1817 - 1821 (2013/04/10)
BLA=0? Not so fast! A series of tetraarylcumulenes up to the length of a [9]cumulene has been synthesized and analyzed by X-ray crystallography. The structural data show a distinct reduction in bond-length alternation (BLA) as a function of molecule length, but this trend appears to reach a limit before a cumulenic structure with BLA=0 is achieved. Copyright
Steric tuning of C2-symmetric chiral N-heterocyclic carbene in gold-catalyzed asymmetric cyclization of 1,6-enynes
Yamada, Ken-Ichi,Matsumoto, Yasumasa,Selim, Khalid B.,Yamamoto, Yasutomo,Tomioka, Kiyoshi
experimental part, p. 4159 - 4165 (2012/07/27)
Steric tuning of C2-symmetric chiral N-heterocyclic carbene (NHC) was performed in Au(I)-catalyzed asymmetric cyclization of 1,6-enyne. Higher enantioselectivity was realized when chiral NHC-AuCl/AgSbF6 catalysts whose N-substituent on the NHC overlays the Au-Cl bond was utilized.
