6295-89-2Relevant academic research and scientific papers
The versatile reactivity of 2-aryl-4,6-dinitrobenzotriazole 1-oxides in diels-alder type condensations and in σ-complexation - A relationship between superelectrophilicity and pericyclic reactivity
Vichard, Dominique,Boubaker, Taoufik,Terrier, Francois,Pouet, Marie-Jose,Dust, Julian M.,Buncel, Erwin
, p. 1617 - 1623 (2007/10/03)
A two-pronged study of a series of 2-aryl-4,6-dinitrobenzotriazole 1-oxide substrates (2a-c) is reported: Diels-Alder type pericyclic reactivity and covalent hydration to yield Meisenheimer type hydroxy anionic σ-adducts. The most activated benzotriazole
