629618-19-5

Upstream product

• 103791-04-4 Benzyloxymethyl isopropenyl ketone 
• 629618-18-4 (3R,6S)-2-(4-Benzyloxy-2-methyl-3-oxo-butyl)-3-[(R)-2-(tert-butyl-diphenyl-silanyloxy)-1-methyl-ethyl]-6-methyl-cyclohexanone 
• 629618-17-3 (2S,5S)-5-[(R)-2-(tert-Butyl-diphenyl-silanyloxy)-1-methyl-ethyl]-2-methyl-cyclohexanone 
• 122999-66-0 2-methyl-5-[2-hydroxy-1-methylethyl]cyclohexanone 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 630110-07-5 (5R,8S)-1-Benzyloxy-5-[(R)-2-(tert-butyl-diphenyl-silanyloxy)-1-methyl-ethyl]-8a-hydroxy-3,8-dimethyl-octahydro-naphthalen-2-one 

Downstream Products

• 629618-23-1 6-[2-(tert-butyl-diphenyl-silanyloxy)-1-methyl-ethyl]-4,9-dimethyl-6,7,8,9-tetrahydro-3H-1-oxa-3-aza-cyclopenta[a]naphthalen-2-one 
• 629618-32-2 N-{5-[2-(tert-butyl-diphenyl-silanyloxy)-1-methyl-ethyl]-1-hydroxy-3,8-dimethyl-5,6,7,8-tetrahydro-naphthalen-2-yl}-acetamide 
• 629618-27-5 Methanesulfonic acid (5R,8S)-2-acetylamino-5-[(R)-2-(tert-butyl-diphenyl-silanyloxy)-1-methyl-ethyl]-3,8-dimethyl-5,6,7,8-tetrahydro-naphthalen-1-yl ester 
• 629618-22-0 N-{1-benzyloxy-5-[2-(tert-butyl-diphenyl-silanyloxy)-1-methyl-ethyl]-3,8-dimethyl-5,6,7,8-tetrahydro-naphthalen-2-yl}-acetamide 

Relevant academic research and scientific papers

First Enantiospecific Total Synthesis of the Antitubercular Marine Natural Product Pseudopteroxazole. Revision of Assigned Stereochemistry

A concise, enantiospecific synthesis of pseudopteroxazole (3), which had originally been assigned structure 1, has been accomplished starting from S-(-)-limonene. The known cyclohexanone 5 was converted in five steps to the α,β-enone 8 by a modified Robin