62965-15-5Relevant academic research and scientific papers
Magnetic-field-dependent 1H relaxivity behavior of biotin/avidin-based magnetic resonance imaging probes
Verma, Kirti Dhingra,Mishra, Anurag,Engelmann, Joern,Beyerlein, Michael,Maier, Martin E.,Logothetis, Nikos K.
, p. 758 - 769 (2012)
One major challenge in noninvasive mapping of various molecular targets is their inherently low in vivo concentration coupled with the insensitivity of imaging modalities, such as the widely used magnetic resonance imaging (MRI). Development of agents wit
Light-mediated deoxygenation of alcohols with a dimeric gold catalyst
McCallum, Terry,Slavko, Ekaterina,Morin, Mathieu,Barriault, Louis
supporting information, p. 81 - 85 (2015/02/18)
A new protocol for the reductive deoxygenation of primary alcohols was explored. This photo-mediated method combines a novel approach to bromination of alcohols merged with the powerful reducing capability of [Au2(dppm)2]Cl2 [dppm = 1,1-bis(diphenylphosphino)methane] as a photoredox catalyst. The highly efficient methods discussed are marked by the use of UVA light-emitting diodes, which have significantly reduced reaction times and lowered setup cost.
Visible-light-mediated conversion of alcohols to halides
Dai, Chunhui,Narayanam, Jagan M.R.,Stephenson, Corey R.J.
experimental part, p. 140 - 145 (2012/02/06)
The development of new means of activating molecules and bonds for chemical reactions is a fundamental objective for chemists. In this regard, visible-light photoredox catalysis has emerged as a powerful technique for chemoselective activation of chemical bonds under mild reaction conditions. Here, we report a visible-light-mediated photocatalytic alcohol activation, which we use to convert alcohols to the corresponding bromides and iodides in good yields, with exceptional functional group tolerance. In this fundamentally useful reaction, the design and operation of the process is simple, the reaction is highly efficient, and the formation of stoichiometric waste products is minimized.
Coordination chemistry of phosphanyl amino acids: Solid state and solution structures of neutral and cationic rhodium complexes
Meyer, Christian,Scherer, Markus,Schoenberg, Hartmut,Rueegger, Heinz,Loss, Sandra,Gramlich, Volker,Gruetzmacher, Hansjoerg
, p. 137 - 148 (2007/10/03)
Copper phosphide or arsenide complexes, [Cu(EPh2)(neo)] (E = P, As, neo = 2,9-dimethyl-1,10-phenanthroline; trivial name: neocuprine) react selectively with the N-protected brominated serine derivatives, 2-(S)-(alkoxycarbonylamino)-3-bromomethy
One pot conversion of alcohols to disulfides mediated by benzyltriethylammonium tetrathiomolybdate
Sinha, Surajit,Ilankumaran,Chandrasekaran
, p. 14769 - 14776 (2007/10/03)
A one pot conversion of alcohols to disulfides in good yields via the activation of a hydroxyl group with DCC or P(NMe2)3 / CCl4 followed by treatment with benzyltriethylammonium tetrathiomolybdate is reported.
