62992-84-1Relevant academic research and scientific papers
Reactions of gem-Dihalophenylcyclopropanes with Nucleophilic Agents: Formation of Phenylcyclopropanone and 2-Phenylpropenal Acetals
Kostikov,Varakin,Molchanov,Ogloblin
, p. 25 - 30 (2007/10/03)
Reactions of gem-dihalophenylcyclopropanes with alcohols in dimethyl sulfoxide in the presence of potassium tert-butoxide yield phenylcyclopropanone acetals. Reactions with alcohols in the presence of potassium hydroxide at 80-100°C yield cyclopropanone and 2-phenylpropenal acetals; their ratio depends mostly on the nature of the nucleophile.
Reactions of gem-Dihalocyclopropanes with Nucleophilic Agents: Formation of Acetylene Derivatives and Reaction Mechanism
Kostikov,Varakin,Molchanov,Ogloblin
, p. 31 - 35 (2007/10/03)
Heating of gem-dibromocyclopropanes with potassium hydroxide in alcohols yields cyclopropanone acetals and 2-propynyl ethers. The mechanism of formation of these compounds is discussed.
