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3-(4-phenylphenyl)cyclohex-2-en-1-one is a complex organic compound characterized by a cyclohexenone ring, which is a six-membered carbon ring with a double bond between two of the carbons. The molecule features a phenyl group (a benzene ring) attached to the cyclohexenone at the 4-position, and another phenyl group attached to the first phenyl group at the para position (the 4-position relative to the first phenyl group). 3-(4-phenylphenyl)cyclohex-2-en-1-one is known for its potential applications in the synthesis of various pharmaceuticals and agrochemicals due to its unique structure and reactivity. It is a white crystalline solid and is typically synthesized through a series of chemical reactions involving cyclohexanone and phenyl compounds. The compound's properties, such as its melting point, solubility, and reactivity, can be influenced by the presence of these phenyl groups, making it a versatile building block in organic chemistry.

6301-53-7

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6301-53-7 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 6301-53-7 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 6,3,0 and 1 respectively; the second part has 2 digits, 5 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 6301-53:
(6*6)+(5*3)+(4*0)+(3*1)+(2*5)+(1*3)=67
67 % 10 = 7
So 6301-53-7 is a valid CAS Registry Number.
InChI:InChI=1/C18H16O/c19-18-8-4-7-17(13-18)16-11-9-15(10-12-16)14-5-2-1-3-6-14/h1-3,5-6,9-13H,4,7-8H2

6301-53-7SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name 3-(4-phenylphenyl)cyclohex-2-en-1-one

1.2 Other means of identification

Product number -
Other names 3-Biphenyl-4-yl-cyclohex-2-enon

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

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More Details:6301-53-7 SDS

6301-53-7Relevant academic research and scientific papers

Fe2(CO)9-mediated [5+1] cycloaddition of vinylcyclopropanes and CO for the synthesis of α, β-cyclohexenones

Liu, Cheng-Hang,Zhuang, Zhe,Bose, Sritama,Yu, Zhi-Xiang

supporting information, p. 2752 - 2755 (2016/05/19)

A Fe2(CO)9-mediated [5+1] cycloaddition of vinylcyclopropanes (VCPs) and CO to α, β-cyclohexenones has been developed. The reaction can tolerate aryl and aliphatic groups at the α-position of VCPs, while VCP substrates with vinyl or alkynyl substitutions are not suitable ones. In addition, this reaction can also be used to synthesize bicyclic rings if an aryl group is attached to the vinyl moiety of the substrate. Compared to the Fe(CO)5-mediated [5+1] reaction, the use of cheap and safe Fe2(CO)9 and abandoning the photo-irradiation conditions are the two major advantages of the present method.

Copper/Selectfluor-System-Catalyzed Dehydration-Oxidation of Tertiary Cycloalcohols: Access to β-Substituted Cyclohex-2-enones, 4-Arylcoumarins, and Biaryls

Ren, Shaobo,Zhang, Jian,Zhang, Jiahui,Wang, Heng,Zhang, Wei,Liu, Yunkui,Liu, Miaochang

supporting information, p. 5381 - 5388 (2015/08/24)

A route to β-substituted cyclohex-2-enones, 4-arylcoumarins, and biaryls has been developed. This approach involves a one-pot Cu0/Selectfluor-catalyzed dehydration-oxidation of tertiary cycloalcohols. Thus, by using 2 equiv. of Selectfluor at 25 C, the dehydration-oxidation of tertiary cyclohexanols and oxabenzocyclohexanols gave β-substituted cyclohex-2-enones and 4-arylcoumarins, respectively; whereas the dehydration-oxidation of tertiary cyclohexanols gave biaryls as the final products by using 2.5 equiv. of Selectfluor at 80 C. A route to β-substituted cyclohex-2-enones, 4-arylcoumarins, and biaryls has been developed. This approach involves a one-pot Cu0/Selectfluor-catalyzed dehydration-oxidation of tertiary cycloalcohols.

Aerobic oxidative heck/dehydrogenation reactions of cyclohexenones: Efficient access to meta-substituted phenols

Izawa, Yusuke,Zheng, Changwu,Stahl, Shannon S.

supporting information, p. 3672 - 3675 (2013/04/23)

Jockeying for the (meta)position: A new dicationic palladium(II) catalyst, employing a 6,6′-dimethyl-2,2′-bipyridine ligand, promotes both the aerobic oxidative Heck coupling and dehydrogenation reactions of cyclohexenones. These reactions may be combined in a one-pot sequence to enable the straightforward synthesis of meta-substituted phenols (see scheme). Copyright

Chemoselective three-component coupling via a tandem Pd-catalyzed boron-Heck and Suzuki reactions

O'Neill, Justin,Yoo, Kyung Soo,Jung, Kyung Woon

body text, p. 7307 - 7310 (2009/04/14)

A new approach is herein reported to prepare biaryl derivatives via a tandem Pd-catalyzed boron-Heck and Suzuki reactions. This one-pot tandem process avoided purification or addition of extra catalyst between steps. The resulting biaryl compounds can be

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