630104-53-9

Upstream product

• 162635-53-2 2,3-O-isopropylidene-5-O-(1-methoxy-1-methyl-ethyl)-D-ribono-1,4-lactone 
• 5336-08-3 D-Ribono-1,4-lactone 
• 681277-20-3 (2S,3S,3aS,9aR)-2-(2,4-Dimethoxy-pyrimidin-5-yl)-5,5,7,7-tetraisopropyl-tetrahydro-1,4,6,8-tetraoxa-5,7-disila-cyclopentacycloocten-3-ol 
• 896442-50-5 C₃₂H₅₂N₂O₈Si₂ 
• 1054610-00-2 2,4-Dimethoxy-5-[(1aS,3aS,4S,5S,6aS,6bS)-4-(4-methoxy-benzyloxy)-hexahydro-1,3,6-trioxa-cyclopropa[e]inden-5-yl]-pyrimidine 
• 630104-45-9 (3aR,6R,6aR)-4-(2',4'-dimethoxypyrimidin-5'-yl)-6-[(1''-methoxy-1''-methylethoxy)methyl]-2,2-dimethyltetrahydro-furo[3,4-d][1,3]dioxol-4-ol 
• 630104-47-1 2,4-Dimethoxy-5-[(3aS,4S,6R,6aR)-6-(1-methoxy-1-methyl-ethoxymethyl)-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl]-pyrimidine 
• 68168-19-4 (2S,3S,4R,5R)-2-(2,4-dimethoxypyrimidin-5-yl)-5-hydroxymethyltetrahydrofuran-3,4-diol 
• 630104-51-7 (2S,3S,4R,5R)-4-allyloxy-2-(2',4'-dimethoxypyrimidin-5'-yl)-3-(p-methoxybenzyloxy)-5-vinyltetrahydrofuran 
• 630104-50-6 (2S,3S,4R,5R)-5-(2',4'-dimethoxypyrimidin-5'-yl)-4-(4'-methoxybenzyloxy)-2-vinyltetrahydrofuran-3-ol 
• 630104-52-8 2,4-dimethoxy-5-[3,7-anhydro-5,6-dideoxy-2-O-para-methoxybenzyl-D-glycero-β-D-allo-hepto-5-enofuranosyl]pyrimidine 
• 630104-48-2 2,4-Dimethoxy-5-[(2S,3S,3aR,9aR)-5,5,7,7-tetraisopropyl-3-(4-methoxy-benzyloxy)-tetrahydro-1,4,6,8-tetraoxa-5,7-disila-cyclopentacycloocten-2-yl]-pyrimidine 
• 630104-46-0 (R)-1-{(4R,5S)-5-[(R)-(2,4-Dimethoxy-pyrimidin-5-yl)-hydroxy-methyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-2-(1-methoxy-1-methyl-ethoxy)-ethanol 
• 630104-49-3 C₃₁H₅₂N₂O₉Si₂ 

Downstream Products

• 896440-52-1 5-[(2S,3S,3aR,6S,7R,7aR)-7-Azido-6-ethoxy-3-(4-methoxy-benzyloxy)-hexahydro-furo[3,2-b]pyran-2-yl]-2,4-dimethoxy-pyrimidine 
• 630104-54-0 (2S,3S,3aR,6S,7R,7aR)-7-azido-2-(2',4'-dimethoxypyrimidin-5'-yl)-6-methoxy-3-(p-methoxybenzyloxy)-hexahydro-2H-furo[3,2-b]pyran 

Relevant academic research and scientific papers

Total synthesis of malayamycin A and analogues

The total synthesis of the bicyclic C-nucleoside malayamycin A is described starting with d-ribonolactone. A new method was developed to obtain preparatively important quantities of β-pseudouridine, which was used as an intermediate. The synthesis of a ca

PROCESS TO PREPARE MALAYAMYCIN DERIVATIVES

A process is provided for the preparation of a compound of the general formula (I): wherein R is H or C1-4 alkyl, which comprises treating a compound of the general formula (II): where R" is R or R8CO, R is as defined above, R8

Total Synthesis and Structural Confirmation of Malayamycin A: A Novel Bicyclic C-Nucleoside from Streptomyces malaysiensis

(Equation presented) The stereocontrolled synthesis of malayamycin A, a novel naturally occurring bicyclic C-nucleoside of the perhydrofuropyran type, is described.