6304-33-2Relevant articles and documents
Ni-catalyzed reductive decyanation of nitriles with ethanol as the reductant
Wu, Ke,Ling, Yichen,Sun, Nan,Hu, Baoxiang,Shen, Zhenlu,Jin, Liqun,Hu, Xinquan
supporting information, p. 2273 - 2276 (2021/03/09)
A nickel-catalyzed reductive decyanation of aromatic nitriles has been developed, in which the readily available and abundant ethanol was applied as the hydride donor. Various functional groups on the aromatic rings, such as alkoxyl, amino, imino and amide, were compatible in this catalytic protocol. Heteroaryl, benzylic and alkenyl nitriles were also tolerated. Mechanistic investigation indicated that ethanol provided hydride efficientlyviaβ-hydride elimination in this reductive decyanation.
Cyanation of aromatic/vinylic boronic acids with α-cyanoacetates
Wang, Xian-Jin,Zhang, Song-Lin
supporting information, p. 14826 - 14830 (2017/12/15)
A friendly protocol is reported to achieve cyanation of aromatic and vinylic boronic acids using nontoxic and readily available α-cyanoacetates as a cyano source under aerobic conditions. Many aryl/vinyl boronic acids (as well as some iodides and bromides) are amenable substrates to give aryl nitriles and acrylonitriles. This cyanation method provides a safe and operationally convenient alternative to traditional ones requiring toxic cyanide salts.
Exploring highly efficient light conversion agents for agricultural film based on aggregation induced emission effects
Qi, Yunpeng,Wang, Yongtao,Yu, Yongjiang,Liu, Zhiyong,Zhang, Yan,Qi,Zhou, Changtong
, p. 11291 - 11297 (2016/12/09)
Aggregation-induced emission (AIE) is a unique photo-physical phenomenon that has become an emerging and hot research area. It has a wide range of applications due to its excellent luminous properties. In this paper, five compounds and their corresponding light conversion films were prepared based on AIE effects and the thermally activated delayed fluorescence (TADF) phenomenon. Furthermore, ultraviolet conversion, dispersion and photo-physical properties such as UV-vis spectra, fluorescence spectra, and photo stability as well as the mechanical properties of the light conversion films were investigated in detail. The results reveal that triphenylacrylonitrile (TPA) exhibits excellent photo stability and ultraviolet light conversion properties. In addition, the fluorescence emission spectrum of TPA corresponds well with the absorption spectrum of plants in the blue-violet region. In particular, the light conversion film with added TPA also shows enhanced mechanical properties and slightly lower visible light transmittance (3.79%) compared to PVC blank film. Based on the photo stabilities of the five compounds, it can be concluded that the electron-withdrawing cyano group can increase the photo stability of TPA, while carbazole substituents are proved to have an uncertain effect on the rate of photo oxidation, which is attributed to the electron-donating properties of carbazole and increased molecular distortion or rigidity. Finally, it is worth mentioning that this is the first report utilizing AIE-active luminogens (AIEgens) in agricultural light conversion film.