63048-67-9Relevant academic research and scientific papers
REACTION OF 1-LITHIO (PHENYLSULFINYL)CYCLOPROPANE WITH ELECTROPHILES: AN ALTERNATIVE SYNTHESIS OF 1-ALKYL- AND 1-(1-HYDROXYALKYL)-(PHENYLSULFINYL)CYCLOPROPANES
Pohmakotr, Manat,Sithikanchanakul, Srisamorn
, p. 3011 - 3020 (2007/10/02)
The reaction of 1-lithiuo (phenylsulfinyl)cyclopropane with various electrophiles was studied.The reductive deoxygenation of the resulting adducts with TiCl4/Zn provided 1-substituted (phenylsulfinyl)cyclopropanes.
A New and Convenient Synthetic Method for Cyclopropyl Phenyl Sulfides
Tanaka, Kazuhiko,Uneme, Hideki,Matsui, Shuichi,Kaji, Aritsune
, p. 2965 - 2972 (2007/10/02)
The reactions of a variety of 1,3-bis(phenylthio)propanes with butyllithium have been shown to produce cyclopropyl phenyl sulfides in good to high yields.A new and convenient in situ preparation of 1-lithiocyclopropyl phenyl sulfide can be readily carried out by treating 1,3-bis(phenylthio)propane with 2 equiv. of butyllithium at 0 degC in THF.The reaction with electrophiles proceeds in good yield.O-Aryl and O-alkyl S-cyclopropyl dithiocarbonates also can be prepared in good yields. 1,2-Bis(phenylthio)ethane was converted to phenyl vinyl sulfide on treatment with butyllithium, while 1,4-bis(phenylthio)butane was recovered unchanged by a similar treatment.
