63101-50-8

Basic information

• Product Name: Formaldehyde-13C, d2 solution
• Synonyms: Formaldehyde-13C, d2 solution;ForMaldehyde-13C (~20% in D2O);ForMaldehyde-13C,D2;ForMaldehyde-13C,D2 (20% in D2O);13C and deuterium labeled formaldehyde;Formalin-13C,d2
• CAS NO: 63101-50-8
• Molecular Formula: CH₂O
• Molecular Weight: 0
• Product Categories: E-FPesticides&Metabolites;Alphabetical Listings;Biomolecular MS;Chemical Labeling ProductsStable Isotopes;Fungicides;LabeledPesticides;Others;Pesticides;Stable Isotopes;Isotope Labelled Compounds, Miscellaneous Reagents
• Mol File: 63101-50-8.mol
• Article Data: 2

Chemical Properties

• Flash Point: 113 °C
• Appearance: /
• CAS DataBase Reference: Formaldehyde-13C, d2 solution(CAS DataBase Reference)
• NIST Chemistry Reference: Formaldehyde-13C, d2 solution(63101-50-8)
• EPA Substance Registry System: Formaldehyde-13C, d2 solution(63101-50-8)

Safety Data

• Hazard Codes: Xn
• Statements: 20/21/22-36/37/38-40-43
• Safety Statements: 26-36/37-51
• RIDADR: UN 3334
• WGK Germany: 3
• Hazardous Substances Data: 63101-50-8(Hazardous Substances Data)

Usage

Uses

(Formaldehyde-13C, d2) Labelled Formaldehyde, used in various organic synthesis and reactions. It is used in the textile industry in the area of crosslinking molecules to vary the properties of fabrics. In the food industry it is used to reinforce and improve packaging of meats and produce. It can help improve the water resistance of biodegradable collagen films.

Upstream product

• 1641-69-6 [13C]Carbon monoxide 

Downstream Products

• 1217729-73-1 [(13)CD3]-asenapine 
• 1225035-86-8 C₇⁽¹³⁾CH₇⁽²⁾H₂ClO 

Relevant articles and documents

Selective Conversion of Carbon Dioxide to Formaldehyde via a Bis(silyl)acetal: Incorporation of Isotopically Labeled C1 Moieties Derived from Carbon Dioxide into Organic Molecules

The conversion of carbon dioxide to formaldehyde is a transformation that is of considerable significance in view of the fact that formaldehyde is a widely used chemical, but this conversion is challenging because CO2 is resistant to chemical transformations. Therefore, we report here that formaldehyde can be readily obtained from CO2 at room temperature via the bis(silyl)acetal, H2C(OSiPh3)2. Specifically, formaldehyde is released from H2C(OSiPh3)2 upon treatment with CsF at room temperature. H2C(OSiPh3)2 thus serves as a formaldehyde surrogate and provides a means to incorporate CHx (x = 1 or 2) moieties into organic molecules. Isotopologues of H2C(OSiPh3)2 may also be synthesized, thereby providing a convenient means to use CO2 as a source of isotopic labels in organic molecules.