63104-53-0

Basic information

• Product Name: 3-Cyclohexene-1-carboxylic acid, 3-methyl-5-oxo-, methyl ester
• CAS NO: 63104-53-0
• Molecular Formula: C9H12O3
• Molecular Weight: 168.192
• Mol File: 63104-53-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 3-Cyclohexene-1-carboxylic acid, 3-methyl-5-oxo-, methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Cyclohexene-1-carboxylic acid, 3-methyl-5-oxo-, methyl ester(63104-53-0)
• EPA Substance Registry System: 3-Cyclohexene-1-carboxylic acid, 3-methyl-5-oxo-, methyl ester(63104-53-0)

Safety Data

• Hazardous Substances Data: 63104-53-0(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 19698-24-9 1,3-Diacetyl-tricarballylsaeure-triethylester 
• 63104-52-9 Diacetonylmalonsaeuredimethylester 
• 181478-00-2 methyl 2-(prop-2-yn-1-yl)pent-4-ynoate 
• 40870-15-3 ethyl 2-(prop-2-yn-1-yl)pent-4-ynoate 
• 63104-44-9 dimethyl 2,2-di(prop-2-ynyl)malonate 

Relevant articles and documents

Platinum-catalyzed hydrative cyclization of 1,6-diynes for the synthesis of 3,5-substituted conjugated cyclohexenones

We have developed a Pt(COD)Cl2-catalyzed hydrative cyclization of 1,6-diynes leading to the formation of functionalized cyclohexenones in good yields.

Synthesis of 2-cyclohexenone derivatives via gold(I)-catalyzed hydrative cyclization of 1,6-diynes

(Chemical Equation Presented) The gold(I) complex (MeAuPPh3) was found to be a highly effective catalyst for the hydrative cyclization of 1,6-diynes to form the corresponding 3-methyl hex-2-enone derivatives with good to excellent yield. The proposed mechanism is described.