6312-13-6Relevant academic research and scientific papers
One-pot β-substitution of enones with alkyl groups to β-alkyl enones
Matsuo, Jun-Ichi,Aizawa, Yayoi
, p. 2399 - 2401 (2007/10/03)
Vinylic hydrogens at the β-position of enones were effectively substituted with alkyl groups in a one-pot procedure to afford β-alkyl enones in good to high isolated yields by conjugate addition of higher-order dialkyl cyanocuprates to enones, followed by a reaction with N-tert-butylbenzenesulfinimidoyl chloride at -78 °C. The Royal Society of Chemistry 2005.
