6312-86-3 Usage
General Description
2-(3-nitrophenoxy)Benzoic acid is a chemical compound with the molecular formula C13H9NO5. It is a white to yellow crystalline powder that is typically used in the manufacturing of dyes, pharmaceuticals, and agricultural chemicals. 2-(3-nitrophenoxy)Benzoic acid is also known for its anti-inflammatory properties and is used as an active ingredient in certain topical ointments and creams. Its chemical structure contains a benzoic acid group fused with a nitrophenyl ring, which gives it its distinctive characteristics and potential applications in various industries. However, it is important to handle this compound with care due to its potential hazards and toxic nature.
Check Digit Verification of cas no
The CAS Registry Mumber 6312-86-3 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 6,3,1 and 2 respectively; the second part has 2 digits, 8 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 6312-86:
(6*6)+(5*3)+(4*1)+(3*2)+(2*8)+(1*6)=83
83 % 10 = 3
So 6312-86-3 is a valid CAS Registry Number.
InChI:InChI=1/C13H9NO5/c15-13(16)11-6-1-2-7-12(11)19-10-5-3-4-9(8-10)14(17)18/h1-8H,(H,15,16)
6312-86-3Relevant articles and documents
Efficient Aryl Migration from an Aryl Ether to a Carboxylic Acid Group To Form an Ester by Visible-Light Photoredox Catalysis
Wang, Shao-Feng,Cao, Xiao-Ping,Li, Yang
, p. 13809 - 13813 (2017/10/24)
We have developed a highly efficient aryl migration from an aryl ether to a carboxylic acid group through retro-Smiles rearrangement by visible-light photoredox catalysis at ambient temperature. Transition metals and a stoichiometric oxidant and base are avoided in the transformation. Inspired by the high efficiency of this transformation and the fundamental importance of C?O bond cleavage, we developed a novel approach to the C?O cleavage of a biaryl ether to form two phenolic compounds, as demonstrated by a one-pot, two-step gram-scale reaction under mild conditions. The aryl migration exhibits broad scope and can be applied to the synthesis of pharmaceutical compounds, such as guacetisal. Primary mechanistic studies indicate that the catalytic cycle occurs by a reductive quenching pathway.
