63131-38-4Relevant academic research and scientific papers
Access to β-keto esters by palladium-catalyzed carbonylative coupling of aryl halides with monoester potassium malonates
Korsager, Signe,Nielsen, Dennis U.,Taaning, Rolf H.,Skrydstrup, Troels
supporting information, p. 9763 - 9766 (2013/09/23)
New tricks for an old dog: The Pd-catalyzed carbonylative α-arylation of monoethyl potassium malonates with aryl bromides and reactive aryl chlorides provides a simple and direct route to aryl β-ketoesters. Because only stoichiometric amounts of carbon monoxide are employed, the method is ideal for the introduction of carbon isotopes into more complex structures. Copyright
