63170-98-9Relevant academic research and scientific papers
Surfactant-type Bronsted acid catalyzed dehydrative nucleophilic substitutions of alcohols in water
Shirakawa, Seiji,Kobayashi, Shu
, p. 311 - 314 (2007)
(Chemical Equation Presented) A protocol for the dehydrative nucleophilic substitution of benzyl alcohols with a variety of carbon- and heteroatom-centered nucleophiles using dodecylbenzenesulfonic acid (DBSA) as a surfactant-type Bronsted acid catalyst i
Fluorinated Alcohol-Promoted Reaction of Chlorohydrocarbons with Diverse Nucleophiles for the Synthesis of Triarylmethanes and Tetraarylmethanes
Yu, Liping,Li, Shuai-Shuai,Li, Weina,Yu, Shitao,Liu, Qing,Xiao, Jian
, p. 15277 - 15283 (2019/01/04)
This article reports an efficient synthesis of triarylmethanes and tetraarylmethanes from chlorohydrocarbons with miscellaneous nucleophiles in fluorinated alcohols, featuring metal-free, wide substrate scope, excellent functional group tolerance, and mild reaction conditions.
Direct benzylation and allylic alkylation in high-temperature water without added catalysts
Hirashita, Tsunehisa,Kuwahara, Sho,Okochi, Sota,Tsuji, Makoto,Araki, Shuki
experimental part, p. 1847 - 1851 (2010/09/07)
In high-temperature water a series of benzyl and allylic alcohols reacted with 1,3-dicarbonyl compounds and activated aromatic compounds to give the alkylated products without added catalysts.
DUAL TYPE OF REACTIVITY OF 1,2-DISUBSTITUTED DIHYDRO-N-HETEROAROMATIC SYSTEMS. 11. AROMATIZATION OF N-SULFONYL-1,2-DIHYDROQUINOLINES AND ISOQUINOLINES CONTAINING AN α-INDOLYL OR PYRROLYL SUBSTITUENT
Chmilenko, T. S.,Nezdiiminoga, T. N.,Sidorenko, L. M.,Sheinkman, A. K.
, p. 1226 - 1228 (2007/10/02)
When N-sulfonyl-1,2-dihydroquinolines and isoquinolines, containing an indolyl or pyrrolyl substituent at the α-position, react with trityl perchlorate, this substituent is split off, and N-sulfonyl quinolinium and isoquinolinium cations and tritylindole or tritylpyrrole are formed.A similar reaction with 2,2,6,6-tetramethyl-1-oxopiperidinium perchlorate proceeds with splitting of hydrogen or retention of the α-substituent, which leads to the corresponding α-substituted N-sulfonylquinolinium and isoquinolinium cations.
