631869-32-4Relevant academic research and scientific papers
Synthesis, Characterization, and Reactivity of (Fluoroalkyl)- and (Fluorocycloalkyl)cobaloximes: Molecular Structure of a (2-Fluorocyclohexyl)cobaloxime Complex and Hindered Rotation of 2-Fluorocycloalkyl Ligands
Galinkina, Jelena,Rusanov, Eduard,Wagner, Christoph,Schmidt, Harry,Stroehl, Dieter,Tobisch, Sven,Steinborn, Dirk
, p. 4873 - 4884 (2008/10/08)
The preparation of fluoroalkyl and fluorocycloalkyl was discussed. The synthesis and characterization proved that the C-F activation was restricted to fluorine substitution at the β position. Molecular structures of the compound was found to exhibit complexes with an equitorial pseudomacrocyclic ligands as well as axial base and organo ligand in mutually trans positions.
