63191-59-3Relevant academic research and scientific papers
Water-soluble diphosphadiazacyclooctanes as ligands for aqueous organometallic catalysis
Boulanger, Jér?me,Bricout, Hervé,Tilloy, Sébastien,Fihri, Aziz,Len, Christophe,Hapiot, Frédéric,Monflier, Eric
, p. 77 - 81 (2012)
Two new water-soluble diphosphacyclooctanes been synthesized and characterized by NMR and surface tension measurements. Both phosphanes proved to coordinate rhodium in a very selective way as well-defined bidentates were obtained. When used in Rh-catalyzed hydroformylation of terminal alkenes, both ligands positively impacted the reaction chemoselectivity.
