63261-43-8Relevant academic research and scientific papers
Carbonylative Mizoroki-Heck Reaction of Alkyl Iodides with Arylalkenes Using a Pd/Photoirradiation System
Sumino, Shuhei,Ui, Takahito,Hamada, Yuki,Fukuyama, Takahide,Ryu, Ilhyong
supporting information, p. 4952 - 4955 (2015/11/03)
A carbonylative Mizoroki-Heck reaction using alkyl iodides was achieved with a Pd/photoirradiation system using DBU as a base. In this reaction, alkyl radicals were formed from alkyl iodides via single-electron transfer (SET) and then underwent a sequential addition to CO and alkenes to give β-keto radicals. It is proposed that DBU would abstract a proton α to carbonyl to form radical anions, giving α,β-unsaturated ketones via SET.
